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Q: Chemistry - GC & GCMS ( Answered 5 out of 5 stars,   0 Comments )
Question  
Subject: Chemistry - GC & GCMS
Category: Science > Chemistry
Asked by: greatone100-ga
List Price: $2.00
Posted: 01 May 2003 06:27 PDT
Expires: 31 May 2003 06:27 PDT
Question ID: 197922
A gas chromatogram of the organic components of a sample of beer using
a column that separates compounds on the basis of their relative
boiling points provides a GLC trace with several peaks.  Two of the
smaller peaks, with retention times of 9.56 and 16.23 minutes, are
believed to be ethyl acetate and ethyl butyrate, respectively.

Suggest 2 ways in which you could adjust the conditions of the
experiment so as to reduce the retention time for all components in
the sample.
Answer  
Subject: Re: Chemistry - GC & GCMS
Answered By: tehuti-ga on 01 May 2003 13:00 PDT
Rated:5 out of 5 stars
 
Well met again! :)

The retention time can be reduced for all components by using a
shorter column and by increasing the temperature of the column.

Source:
“The retention time (tR) is directly influenced by the column length.
Longer columns cause higher retention times… The column temperature
influences the separation, too. An increased temperature induces a
decrease of the distribution coefficient and the retention time.”
From “Gas chromatography (GC)”
http://www.zal.tu-cottbus.de/zal/prakt/gaschrom.htm (web site of the
Brandenburg Technical University, Cottbus, Germany)

Search strategy: decrease "retention times" "gas chromatography"
greatone100-ga rated this answer:5 out of 5 stars

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