To make a long story short, my youngest daughter decided to endure
through 4 semesters of chemistry, and now is paying up for it. She is
a talented little girl, but science is not her thing and it hurts for
me to see her study so hard but understand so little. It runs in the
family. I wanted to help myself, but me and my wife are no scientists
at all, plus it was so long ago. Tutoring is very very weak at where
she goes, and we know few friends around here who are capable of
helping, most of which already are looking at us the wrong way for
asking so much. I decided to open my pocket and let you, Chemistry
folks, help us out. I secretly took the next set of questions from my
daughters assignment section, and here they are. I understand that
many (or most) of you would have the problem to giving direct help
like this, "learning and understanding the material is the most
important", right ? Wrong. Only but a few of you would understand the
pain I feel when I see my daughter quietly cry in her room over her
low assignment grades after hours and hours of studying daily.
 
Below I copied down some of the questions and choice answers that came
along. I tried my best to copy down everything number to number, word
for word. Its a little bit difficult to transfer everything to text,
but I tried. Please feel free to clarify if you did not understand a
part.
 
I am asking for a list of answers to the problems, in numerical +
content format, as such :
 
Question 1: Answer 3. The number of moles is 4.0. 
Question 2: Answer 5. The reaction is reversed. 
 
Time is an issue, but I would like the answers to be correct. I do not
want to check my daughters answers and tell her that one of her
correct answers is incorrect simply because what was given to me is a
wrong answer. Once again I apologize for such rude question, but I am
desperate, and I ran out of all other options. I am also considering a
big tip for those who'll work hard on these, do all (or most) of the
questions, provide the correct answers and hopefully as soon as
possible.
 
Thank you once more. You are my last hope. 
 
1) 2HgO(s) <-> 2Hg(l) + O2(g) 
 
What is the form of the equilibrium constant, Kc, for the reaction ? 
 
1. Kc = [O2] 
2. Kc = [Hg]^2[O2] 
3. Kc = ([Hg]^2[O2])/[HO]^2 
4. Kc = [O2]/[HgO]^2 
5. None is correct 
 
2) PbO(s) + CO2(g) <-> PbCO3(s) 
 P(species) means pressure of species 
What is the form of the equilibrium constant ? 
 
1. None is correct 
2. Kp = 1/P(CO2) 
3. Kc = [PbCO3]^2/[CO2][PbO] 
4. Kp = P(PbCO3) / P(CO2) 
5. Kp = [PbCO3]/([PbO] * P(CO2)) 
 
3) 2CO(g) + O2(g) <-> 2CO2, relationship between Kc & Kp is 
 
1. Kp = KcRT 
2. Kp = Kc(RT)^-1 
3. Kp = Kc(RT)^-2 
4. Kp = Kc 
5. Kp = Kc(RT)^2 
 
4) The equilibrium constant, Kp, for the following reaction is 280 at
150deg Celcius. Suppose that a quantity of IBr is placed in a closed
reaction vessel and the system is allowed to come to equilibrium at
150deg Celcius. When equilibrium is established, the pressure of IBr
is 0.200 atm. What is the pressure of I2 at equilibrium ?
 
I2(g) + Br2(g) <-> 2IBr(g) + 11.7kJ 
 
1. 0.012 
2. 0.096 
3. none 
4. 0.0168 
5. 0.067 
 
5) Kc = 0.040 for the system below at 450deg Celcius 
 
PCl5(g) <-> PCl3(g) + Cl2(g) 
 
What is Kp at 450 deg Celcius ? 
 
1. 0.40 
2. 0.64 
3. 5.2 * 10^-2 
4. 2.4 
5. 6.7 * 10^-4 
 
6 C) Given that Co2(g) reacts with C(s) via the reaction 
 
C(s) + CO2(g) <-> 2CO(g) 
 
and Kp = 1.90 atm, what is the equilibrium partial pressure of CO2 if
1.00 atm of CO2 is placed in a vessel wth PURE SOLID CARBON ? (No CO
initially)
 
1. 0.55atm 
2. 0.85atm 
3. 0.60atm 
4. 0.43atm 
5. 0.51atm