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Q: balancing acid-base rxns ( Answered 5 out of 5 stars,   2 Comments )
Question  
Subject: balancing acid-base rxns
Category: Science > Chemistry
Asked by: shadowrider-ga
List Price: $3.00
Posted: 08 Feb 2004 11:10 PST
Expires: 09 Mar 2004 11:10 PST
Question ID: 304730
What is the balanced equation for the reaction of a strong acid, using
say XCOOH to represent a strong acid, with NaHCO3. Would the rxn be
XCOOH + NaHCO3 goes to XCOO- + Na+ + CO2 + H2O?

What about the balanced equation for the reaction of a weak acid,
using ArOH to represent weak acid, with NaOH?
Answer  
Subject: Re: balancing acid-base rxns
Answered By: supermacman-ga on 08 Feb 2004 13:23 PST
Rated:5 out of 5 stars
 
Hello,
-----------
I tried to address all possibilities in crafting my answer. If you
want a concise answer, simply read the sections with a star or
asterisk (*).
-----------

Almost all carboxylic acids (-COOH) are weak. Thus, I will present two
scenarios for acid + sodium bicarbonate.

Strong acid + sodium bicarbonate
HX + NaHCO3 --> H2CO3 + NaX
H2CO3 --> H20 + CO2 (decomposition of carbonic acid)
N.B. The first line can be written as: HX + NaHCO3 --> H2CO3 + Na+ + X-

example:
HCl + NaHCO3 --> H2CO3 + NaCl
H2CO3 --> H2O + CO2

* Weak acid (-COOH) + sodium bicarbonate
RCOOH + NaHCO3 --> RCOONa + H2CO3
H2CO3 --> H2O + CO2
N.B. Convention has it that R- is used to represent alkyl groups with
a carboxylic acid group. X can be substituted and the above reaction
would make sense; however, in general, X denotes a halogen (chlorine,
fluorine, etc.)
* N.B.2 The first line can be written as: RCOOH + NaHCO3 --> RCOO- +
Na+ + H2CO3. So yes, you are correct. (You simply combined the
neutralisation and the decomposition of carbonic acid into one
equation, which is correct.)

example:
CH3COOH (acetic acid, vinegar) + NaHCO3 --> CH3COONa (sodium acetate) + H2CO3
H2CO3 --> H2O + CO2


As for a weak acid and sodium hydroxide -
You mention that you want ArOH to denote the acid. This corresponds
with an alcohol group or a hydroxide group. Hydroxide groups, as an
ion, do not donate protons and cannot act as acids, since O(-2)
(single doubly-negative oxygen) never forms. Thus, I will assume you
want the reaction between an alcohol and a base. (It must be noted
that alcohols are extremely weak acids.)

For a general alcohol -
R-OH + NaOH --> R-O-Na + H2O
N.B. Can be written as ROH + NaOH --> RO- + Na+ + H2O

* Ar may denote a benzene (aromatic) ring. ArOH would then be phenol,
and the following reaction applies:
ArOH + NaOH --> Ar-O-Na + H2O
N.B. Also can be written as C6H5OH + NaOH --> C6H5O-Na + H2O ... since
a phenyl (aromatic ring) is C6H5.

If you used Ar to denote argon, then it is wrong; there is no such
thing as argon hydroxide (ArOH).

If you have questions about any part of this answer, please use the
"Clarify Answer" function.

Thanks!

- supermacman-ga

Reference
J McMurry, Organic Chemistry, 6th edition, United States of America,
Thomson-Brooks/Cole, 2004.
shadowrider-ga rated this answer:5 out of 5 stars
thank you for the very detailed explanation! That will help me
understand future equations too!

Comments  
Subject: Re: balancing acid-base rxns
From: webdesignerservr-ga on 08 Feb 2004 21:28 PST
 
Also note that when using weak acids, an equilibrium is involved. 
Just Trying to help.

Regards,
webdesignerservr-ga
Subject: Re: balancing acid-base rxns
From: supermacman-ga on 10 Feb 2004 10:39 PST
 
Hello shadowrider-ga:

I'm glad my detail helped you. Sometimes I think I write too much, but
in this case detail was a plus!

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