Hello,
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I tried to address all possibilities in crafting my answer. If you
want a concise answer, simply read the sections with a star or
asterisk (*).
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Almost all carboxylic acids (-COOH) are weak. Thus, I will present two
scenarios for acid + sodium bicarbonate.
Strong acid + sodium bicarbonate
HX + NaHCO3 --> H2CO3 + NaX
H2CO3 --> H20 + CO2 (decomposition of carbonic acid)
N.B. The first line can be written as: HX + NaHCO3 --> H2CO3 + Na+ + X-
example:
HCl + NaHCO3 --> H2CO3 + NaCl
H2CO3 --> H2O + CO2
* Weak acid (-COOH) + sodium bicarbonate
RCOOH + NaHCO3 --> RCOONa + H2CO3
H2CO3 --> H2O + CO2
N.B. Convention has it that R- is used to represent alkyl groups with
a carboxylic acid group. X can be substituted and the above reaction
would make sense; however, in general, X denotes a halogen (chlorine,
fluorine, etc.)
* N.B.2 The first line can be written as: RCOOH + NaHCO3 --> RCOO- +
Na+ + H2CO3. So yes, you are correct. (You simply combined the
neutralisation and the decomposition of carbonic acid into one
equation, which is correct.)
example:
CH3COOH (acetic acid, vinegar) + NaHCO3 --> CH3COONa (sodium acetate) + H2CO3
H2CO3 --> H2O + CO2
As for a weak acid and sodium hydroxide -
You mention that you want ArOH to denote the acid. This corresponds
with an alcohol group or a hydroxide group. Hydroxide groups, as an
ion, do not donate protons and cannot act as acids, since O(-2)
(single doubly-negative oxygen) never forms. Thus, I will assume you
want the reaction between an alcohol and a base. (It must be noted
that alcohols are extremely weak acids.)
For a general alcohol -
R-OH + NaOH --> R-O-Na + H2O
N.B. Can be written as ROH + NaOH --> RO- + Na+ + H2O
* Ar may denote a benzene (aromatic) ring. ArOH would then be phenol,
and the following reaction applies:
ArOH + NaOH --> Ar-O-Na + H2O
N.B. Also can be written as C6H5OH + NaOH --> C6H5O-Na + H2O ... since
a phenyl (aromatic ring) is C6H5.
If you used Ar to denote argon, then it is wrong; there is no such
thing as argon hydroxide (ArOH).
If you have questions about any part of this answer, please use the
"Clarify Answer" function.
Thanks!
- supermacman-ga
Reference
J McMurry, Organic Chemistry, 6th edition, United States of America,
Thomson-Brooks/Cole, 2004. |