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Subject:
Need help - Reduction of benzil w/ NaBH4
Category: Science > Chemistry Asked by: shadowrider-ga List Price: $3.00 |
Posted:
22 Mar 2004 11:40 PST
Expires: 06 Apr 2004 08:39 PDT Question ID: 319224 |
It is sort of 2 questions rolled into 1 - I have to calculate the theoretical yield of meso-hydrobenzoin when 50mg of benzil is rduced with NaBH4 and H2O. So according to what I thought was a balanced equation, it appears that 2 moles of benzil form 2 moles of benzoin. Since the NaBH4 is in excess, the 50mg should be limiting reagent. Given that, I found that moles of benzil in 50mg and that wold equal the moles of hydrobenzoin, which would give me 51mg. But the text says we should 35 mg - what am I doing wrong? I have the reaction as: 4(R2C=O) + NaBH4 gives (R2CHO)4B-Na+ next step: (R2CHO)4B-Na+ + 4H2O gives 4 (R2CHOH) + Na+B(OH)4- I have not been able to find any balanced equations for this reaction online so I don't know if my stochiometry is correct now! Thank you very much! |
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There is no answer at this time. |
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Subject:
Re: Need help - Reduction of benzil w/ NaBH4
From: fstokens-ga on 22 Mar 2004 12:03 PST |
This reaction is more complex than you are taking into account. The question asks for the yield of *meso* hydrobenzoin. |
Subject:
Re: Need help - Reduction of benzil w/ NaBH4
From: fstokens-ga on 22 Mar 2004 13:52 PST |
You might also want to check the structurs/formula of "benzil" and "hydrobenzoin." I can't tell for sure from the way you've written the reaction, but I think you are missing some bits of the molecules. |
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