I assume that you do not want standard reference, or textbook,
but rather direct response to your specific question.
I will do that, but, plese, do ask for clarification, if you feel I did
not answer what you are asking. This is the that type of question
which may require an iteration.
I agree
"that the assumption (of photon having zero amplitude) because
the surfaces' being at thermal equilibrium .."
makes little sense.
More exactly: photon of a given energy corresponds to a an electromagnetic
wave with a given wavelength. There is an electric vector and magnetic vector
and actually only one of them has zero amplitude at the wall.
Which one, that depends on the material of the wall. This is usually not
discussed. For a similar reason, shape of the cavity is not dicussed.
The reason is simple: It has no effect on the final result. So, implicitly,
derivation assumes a rectangular box, and waves are than plane waves,
independent in x y z direction. It is more simple than to assume let's say
an elipsoid. You would get more complex resonant modes, but we only care about
the count at a given energy. So, similarly, if you care which vector
will be zero at the wall, (You have choices Ex, Ey .. Hz or even
mixes of those)
you would make some additional assumptions. Let's say wall being
conductive or not. Either way, the result will be the same.
So, as a specific example let's look at:
http://hyperphysics.phy-astr.gsu.edu/hbase/quantum/rayj.html
There is an equation for Ex
and author says 'the usual':
.." The solution to the wave equation must give zero amplitude at the
walls, since a non-zero value would dissipate energy and violate our
supposition of equilibrium..."
He says Ex (which is better then saying photon) BUT
you can still question that, since the wall is black, and absorbing,
and equilibrium only means that 'on the average' as much of light energy goes
to heat the wall, as much of light is 'emitted' by that wall at that T.
So, you may say (let's say the opposite) the partial d Ex / dx is zero,
rather than Ex, and you will get a different solution than the one shown
(but just the phase will differ) but the number of them, number of solutions,
will be the same.
To use a mechanical analogy: wall of a pipe can be slippery or sticky,
and if you are solving flow of a liquid, you need to select the 'right'
boundary condition, but if you are just counting resonant modes, it will
come out the same. (because number of the degrees of freedom is the same)
as dicussed a bit more here (or Hilbert-Courant textbook etc).
http://people.ccmr.cornell.edu/~muchomas/P214/Notes/IntroWaves/node1.html
So, if you a student of physics, you are getting extra A+ for critical
thinking, and would suggest you look next at Debay's derivation of specific
heat - since it deals with the same issue - counting the degrees of freedom
(in this case of a string) and (forthe same reason as here) it does not matter
if the string ends are fixed, or tied to a elastic rubber band. What
matters is that we need a 'cutoff frequency' - as is apparent apriori,
and as was already recognised by Kelvin, and mentioned in his famous
lecture on the
'two clouds' ...
and that is the true history. If you are interested in history of the
discovery, look at Stephan Brush - books and review articles...
hedgie |