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Subject:
Equilibrium constant
Category: Science > Chemistry Asked by: paulinej-ga List Price: $10.00 |
Posted:
18 Jun 2004 02:14 PDT
Expires: 18 Jul 2004 02:14 PDT Question ID: 362844 |
Methanol can be produced by the following reaction CO + 2H2---CH3OH under the conditions used all are gaseous and concentrations measured in dm-3 1. write equation for K(equilibrium constant) and show units for K 2. explain how the equilibrium yield will be affeced by: - increase in pressue, increase in temperature, increase in concentration of CO & the presence of a catalyst |
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Subject:
Re: Equilibrium constant
Answered By: palitoy-ga on 18 Jun 2004 03:08 PDT Rated: |
Hello Paulinej 1) The equilibrium constant can be given the following equation: K = [CH3OH] / ([CO][H2]^2) If the units are dm-3, that would give units of dm6 for K. Are you sure the units are correct here? dm-3 usually indicates a volume, I would expect something more like mol dm-3 (in which case the answer would be mol2dm6). This is done by examining the units thus: Units of K = dm-3 / dm-3 x (dm-3)(dm-3) Units of K = 1 / dm-6 which is equivalent to dm6 2) Increases in pressure favour the side of the reaction with fewer molecules. On the left hand side of the equation we have 3 mol (one of CO and two of H2), on the right hand side we have 1 mol of CH3OH. Increasing the pressure will therefore increase the yield of CH3OH as the reaction will want to go to the right. Chatelier's Principle states that a reaction will proceed to counteract any change. Therefore an exothermic reaction (one that gives out heat) will favour reactants and endothermic reactions (one that requires heat to start) will favour products when INcreasing the temperature. As your reaction is exothermic the yield will decrease when temperature is increased. An increase in concentration of one of the reactants will will yield more product, this is the process of equilibrium. Therefore increasing the CO concentration should increase the yield of CH3OH. The presence of a catalyst will not effect the yield of the reaction. A catalyst ONLY effects the speed at which equilibrium will be reached (a trick question!). |
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