Basically, you can either use hydro or pyro methods to purify metals
from ores. Each requires the use of various chemical reactions to some
extent. Aluminum is mainly extracted by hydrometallurgy?current is
conducted through a molten bath, and the aluminum is reduced out.
Copper and nickel mainly use pyrometallurgy. For nickel,
pyroextraction uses large furnaces to remove moisture from lateritic
and sulfidic ore and to catalyze the oxidation (burning) of iron and
sulfur that causes the nickel to melt out (this use of oxidation
diminishes the amount of electricity used by utilizing exothermic
reactions). Blast and reverbatory furnaces are no longer allowed
because of pollution, so electric furnaces are used. Check out the
following websites:
http://ifcln1.ifc.org/ifcext/enviro.nsf/AttachmentsByTitle/gui_nickel_WB/$FILE/nickel_PPAH.pdf
http://wbln0018.worldbank.org/essd/essd.nsf/GlobalView/PPAH/$File/54_coppr.pdf
If you actually want to smelt the metals, this website helps:
http://home.europa.com/~heritage/ironsmelt.html
mechanical process is fairly straight forward. The brick lined
furnace, in essence an elongated cauldron of crucible, bosh and stack,
is loaded with a balanced mixture of crushed ore, charcoal and
limestone. Air is pumped into the fire of the bosh and the temperature
of the operation is held at 600 to 1000 degrees Centigrade.
Blowing in the furnace takes several days an must allow for the
moisture contained in the fire-brick lining to evaporate in order to
prevent damage to the furnace. Once the furnace is heated, the
smelting process becomes a continual cycle of top-loading the stack
and drawing off iron from the tap hole and slag from the cinder notch
located near the bottom of the bosh. The mechanical constraints
limiting the size of the bosh are that the furnace be tall enough to
allow the chemical reduction process and small enough that the fuel
(charcoal at Oswego) is able to support the load of ore and flux.
A approximately eighteen month intervals, the furnace is "blown
out" as the lining becomes consumed by the smelting process. Blowing
out is a standard procedure allowing for replacement of the furnace
lining and general examination of the bosh interior. The sporadic
production history of the Oswego smelters can, in part, be attributed
to blowing out and maintaining the stack. |