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Subject:
Organic Chemistry Laboratory Synthesis
Category: Science > Chemistry Asked by: uncross-ga List Price: $10.00 |
Posted:
06 Aug 2004 12:09 PDT
Expires: 05 Sep 2004 12:09 PDT Question ID: 384469 |
What is the reaction mechanism(s) and product(s) for a reaction between 2-oxoethanoic acid and cyclopentadiene? |
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There is no answer at this time. |
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Subject:
Re: Organic Chemistry Laboratory Synthesis
From: dr_bob-ga on 06 Aug 2004 13:29 PDT |
I'll give you a hint. It's a name reaction, pericyclic 6 pi electrons, but not in the classical sense. Good luck with your homework. |
Subject:
Re: Organic Chemistry Laboratory Synthesis
From: uncross-ga on 08 Aug 2004 07:10 PDT |
What name reaction is? Can you give me further hint? |
Subject:
Re: Organic Chemistry Laboratory Synthesis
From: arsenic-ga on 09 Aug 2004 05:54 PDT |
I'll give you a hint: Try using the old name for oxoethanoic acid when searching. |
Subject:
Re: Organic Chemistry Laboratory Synthesis
From: uncross-ga on 09 Aug 2004 07:03 PDT |
I don't even know the old name os 2-oxoethanoic acid. Please, if you know the old name for 2-oxoethanoic acid, would you tell me? |
Subject:
Re: Organic Chemistry Laboratory Synthesis
From: arsenic-ga on 09 Aug 2004 13:46 PDT |
It's glyoxylic acid, try it in a Google search together with cyclopentadiene. (Look up old names in a reference-book like "The Merck Index", or simply search for them using Google next time, you'll learn a lot more: ://www.google.com/search?num=50&hl=en&lr=&ie=UTF-8&safe=off&q=oxoacetic+acid ) |
Subject:
Re: Organic Chemistry Laboratory Synthesis
From: dr_bob-ga on 09 Aug 2004 14:11 PDT |
4 + 2 pi electrons. Two guys are named for it. Very famous... |
Subject:
Re: Organic Chemistry Laboratory Synthesis
From: djredcat-ga on 12 Aug 2004 05:53 PDT |
The recation you're looking for is a Diels-Alder reaction. This is a reaction between a diene and a dieneophile. The dieneophile in this case being the 2-oxoethanoic acid. Usually (of course) the dienephile will be a C=C bond, but in this case the C=O bond acts as the dieneophile. the product is therefore C=C C C O-C COOH hope this helps! |
Subject:
Re: Organic Chemistry Laboratory Synthesis
From: djredcat-ga on 12 Aug 2004 05:59 PDT |
Or for completeness with all H shown: HC=CH H2C CH2 O-CH COOH |
Subject:
Re: Organic Chemistry Laboratory Synthesis
From: dr_bob-ga on 12 Aug 2004 08:46 PDT |
Thank you mr. djred for providing another hint to get him started. Too bad it's not the whole answer. |
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