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Subject:
science/chemistry
Category: Science > Chemistry Asked by: chanard-ga List Price: $5.00 |
Posted:
11 Jul 2002 15:56 PDT
Expires: 10 Aug 2002 15:56 PDT Question ID: 38650 |
what is allyl chlorophenyl carbonate and what are its uses? |
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There is no answer at this time. |
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Subject:
Re: science/chemistry
From: alienintelligence-ga on 11 Jul 2002 22:05 PDT |
Very interesting... Allyl Carbonate: [Plastic] -Less than half the weight of glass -Bright surfaces and light transmissions close to optical glass -Refractive index close to that of crown glass -High impact strength -Remarkable abrasion resistance ( approximately 20 times that of acrylic ) -Resistance to pitting from hot metal sparks, 30 - 40 times higher than glass and other plastics -Excellent resistance to acids, alkalis and to all solvents including aliphatic and aromatic hydrocarbons -Easy surface dying -Better scratch resistance than hard coated plastics -Resistance to distortion by temperatures up to 130° C, a temperature at which acrylic resins are melted -U.V. absorbers can be added to help protect LCD displays in strong sunlight Where does the Chlorophenyl come in? Is it some kinda alien artifact ;-) -AI * I'm still looking, btw |
Subject:
Re: science/chemistry
From: alienintelligence-ga on 11 Jul 2002 22:29 PDT |
Most of the chlorophenyl carbonates I find are connected to hydrocarbons: methane, butane, etc. Is that the way it was written? Any numbers or brackets or parenthesis? -AI |
Subject:
Re: science/chemistry
From: nannyogg-ga on 13 Jul 2002 09:41 PDT |
Allyl Chloro Carbonate: I searched extensively through several chemical datbases, but this threw up no responses. This doesn't necessarliy mean the chemical does not exist, but that there just happens to be little accessible information on it. I searched for similar chemicals:- Allyl Chorocarbonate- A colourless liquid, flammable and corrosive, used as an intermediate in the manufacture of numerous compounds, and in the manufacture of optical lenses. Chlorophenyl Chemicals - These sound particularly nasty; They're dioxins, and can be found in weedkillers, pesticides, herbicides....If it kills something, you'll find this stuff in it! Since the original chemical remains undefinable, I'm left with pure speculation, but this stuff sounds pretty poisonous and unpleasant. I wouldn't be surprised to find it in some top secret cache of chemical weapons somewhere....:-) Great question! |
Subject:
Re: science/chemistry
From: alienintelligence-ga on 13 Jul 2002 15:03 PDT |
I'm thinking it's a plastic of some sort, considering the Allyl Carbonate part. The Chlorophenyl part, Could be an additive to achieve a certain property. It reminds me of chlorophyl, so maybe it's an agent used for filtering of light. Aren't most plastics poisonous when fuming? -AI |
Subject:
Re: science/chemistry
From: robmoon-ga on 18 Jul 2002 15:07 PDT |
Just a point about the meaning of the Chlorophenyl part. This probably has nothing to do with chlorophyll. Chlorophenyl means that the chemical has a group attached to it composing an aromatic ring (benzine- A ring of 6 carbon atoms with alternate single and double bonds and a delocalised Pi orbital)and also a chlorine group attached to it(replacing one of the hydrogens on the ring). This is probably a derivative (with the added chlorophenyl group) of Allyl Carbonate as has already been suggested. It has nothing to do with chlorophyll (doesnt contain chlorine!) which instead derived its name from Greek rather than its chemical formula. |
Subject:
Re: science/chemistry
From: jlchem-ga on 27 Jul 2002 00:03 PDT |
The structure is closely related to plain old allyl carbonate, so it is almost definitely a more sterically hindered way of protecting the carboxyl group in synthetic organic chemistry. To protect the group: Allyl chlorophenyl carbonate, THF, DMAP To deprotect: Me2CuLi, Et2O, 0 degrees C, 1 hr; neutralize with aqueous acid For more information see: K Takeda, A. Akiyama, Y. Konda, H. Takayanagi, and Y. Harigaya, Tetrahedron Letters, 36, 113 (1995) Enjoy |
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