Hello stom,
here is the 101 of these materials
Piezoelectric effect is property of some materials to
change their density in the electric field. Crystals,
quartz for example, and some ceramics have this property.
Here is figure and bit of history:
http://members.tripod.com/~albert51/maz.html
Dpending on how the piece is cut, and where the
field is applied, one can get different deformations:
http://www.dbanks.demon.co.uk/ueng/pztact.html
These effects (there is a whole family of them,
thermoelecttric, photoelastic, ..) are symetric,
meaning: if you bend the piezoelectric plate,
(PZT) it will create voltage. (This is used in some
lighters: the voltage is quiet high and may
produce a spark):
The molecular mechanism is a bit similar to
permanent magnets. The molecules have to be
a aligned so that the effect is not canceled:
http://www.aurelienr.com/electronique/piezo/piezo.pdf
There is no particular theory here. People study
different materials since the effect has many applications
and that research would come under 'statistical mechanics'
and 'irreversible thermodynamics', sometimes rheology.
Example of such a research is here:
http://electroceramics.mit.edu/actuators.html
Some theory and sample circuits is shown here:
http://www.globalspec.com/kistler/ref/tech_theory_text.htm
It is used for sensors, to drive ink-jets, and in quartz clocks,
and older radios a as frequency standard (since the natural resonance
of a crystal
can be excited by an electric circuit.).
It can be used to build tiny electric motors.
They are smaller then conventional ones, since they do not use
magnetic field and do not need coils:
http://www.heason.com/support/piezo_electric_ceramic/downloads/Motor%20Implementations.pdf
That should cover the basics, but feel free to ask for specifics and
indicate if you
want more simple or more technical answer.
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