Although wood alcohol (methanol) can be used as an antifreeze, most
antifreeze products designed for automobiles are a solution of
ethylene glycol and water. The typical full-strength auto antifreeze
product is 95% ethylene glycol and 5% water (a ratio of 19 to 1). It
is designed to be diluted when placed into the automobile's radiator.
"Antifreeze is a mixture of ethylene glycol and water. It actually performs
two functions in an automobile. It depresses the freezing temperature of
water and it elevates the boiling point of water so that your car's cooling
system can operate over a wider temperature range."
MadSci Network: Physics
http://www.madsci.org/posts/archives/dec2001/1008690367.Ph.r.html
"Glycol is the main ingredient used in all forms of antifreeze. Modern
engines use a mixture of glycol and water as a coolant... Most
antifreeze uses ethylene glycol, C2H6O2, but propylene glycol, C3H8O2,
products are becoming more common. Ethylene glycol is less expensive
to produce. Propylene glycol is less toxic."
EET Corporation: Antifreeze Facts
http://www.eetcorp.com/antifreeze/antifreeze-about.htm
"Ethylene glycol is the most widely used automotive cooling-system
antifreeze, although methanol, ethanol, isopropyl alcohol, and
propylene glycol are also used. In automotive windshield-washer
fluids, an alcohol (e.g., methanol) is usually added to keep the
mixture from freezing; it also acts as a solvent to help clean the
glass."
US Environmental Protective Agency: Antifreeze
http://www.epa.gov/epaoswer/non-hw/muncpl/antifree.htm
"Most brands of commercial antifreeze consist of 95 percent ethylene
glycol, an extremely toxic chemical."
Columbia Animal Hospital: Antifreeze Poisoning
http://www.cah.com/library/antifreeze.html
"Nemco Universal Antifreeze & Coolant...
Total Water 5% Max
Total Glycol 95% Min"
NEMCO: Product Data Sheet
http://www.nemco.mb.ca/pdUN_antifreeze.html
Regarding the freezing point, the article linked below has a useful
graph which shows the freezing point of ethylene glycol at different
percentages. Pure antifreeze (95% ethylene glycol), right out of the
bottle, freezes at around -4°F. Diluted antifreeze is more effective,
and a solution of 60% ethylene glycol and 40% water can withstand a
temperature of -60F before slushing and freezing.
"Ethylene glycol, the principal component of most antifreezes, freezes
at 8 degrees above zero, Fahrenheit. It is only when water is added
that the freezing point is depressed. The freezing point of an
ethylene glycol and water mixture drops rapidly as the concentration
of glycol is increased to a mixture of about 60% antifreeze and 40%
water. Around that point, an abrupt turnabout occurs, and as more
antifreeze is added, the freezing point rises almost as fast as it had
previously dropped...
Glycols do not have sharp freezing points, and even below the freezing
temperatures, a slushy solution exists which will still flow. In the
never-never transition zone around -60°F and 60% glycol, the mixture
can either crystallize like water (particularly when 'seeded' by a
crystal and agitated) or set to a glass-like solid with no orderly
internal crystalline structure."
Alaska Science Forum: Don't Fill Her Up with Antifreeze
http://www.gi.alaska.edu/ScienceForum/ASF6/680.html
My Google search strategy:
Google Web Search: antifreeze "ethylene glycol" percent
://www.google.com/search?hl=en&q=antifreeze+%22ethylene+glycol%22+percent
Google Web Search: "ethylene glycol" + "freezing point"
://www.google.com/search?hl=en&q=%22ethylene+glycol%22+%22freezing+point
I hope this is precisely the information you need. If anything is
unclear or incomplete, please request clarification; I'll be glad to
offer further assistance before you rate my answer.
Best regards,
pinkfreud |