I need to know which college class I should take first.  Should I take
College Algebra?  Or should I take Elementary Statistics?  I am new to
college classes and want to take what is generally the easisest to
excel in.

It depends on your major and the college's graduation requirements.
"Elementary statistics" should not be as demanding as "college
algebra". But statistics does become more demanding as it explores
more complex useage. If your major or college requirements lead to
calculus, algebra is a common starting point. The natural sciences,
computer science, economics or business will require greater facility
with algebraic equations that the social sciences or humanities will.
Be sure to ask your college advisor which class is most useful for
you.